|
|
p-coumaric_acid <=> 2,4-dihydroxycinnamic_acid
|
1
|
–
|
| |
MetaCyc:
RXN-14167
|
|
|
|
(Z)-3-(2,4-dihydroxyphenyl)-prop-2-enoate <=> umbelliferone
|
not assigned
|
–
|
| |
MetaCyc:
RXN-14168
|
|
|
|
ferulic_acid + 2-oxoglutarate + O2 <=> (E)-6''-hydroxyferulate + succinate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-14071
|
|
|
|
S-adenosyl-L-methionine + esculetin <=> scopoletin + S-adenosyl-L-homocysteine + H+
|
2.1.1
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.6
catechol O-methyltransferase
|
–
–
–
|
| |
BRENDA:
BS420244
MetaCyc:
RXN-13473
|
|
|
|
S-adenosyl-L-methionine + caffeic_acid <=> H+ + ferulic_acid + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.68
caffeate O-methyltransferase
|
–
–
|
| |
BRENDA:
BR43911
KEGG:
R03366
MetaCyc:
RXN-1104
SABIO-RK:
14976
|
|
|
|
p-coumaric_acid + reduced_[NADPH-hemoprotein_reductase] + O2 <=> caffeic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
MetaCyc:
RXN-1103
|
|
|
|
(Z)-6''-hydroxyferulate <=> scopoletin
|
not assigned
|
–
|
| |
MetaCyc:
RXN-14072
|
|
|
|
UDP-glucose + scopoletin <=> H+ + scopolin + UDP
|
2.4.1.111
coniferyl-alcohol glucosyltransferase
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
2.4.1.128
scopoletin glucosyltransferase
2.4.1.170
isoflavone 7-O-glucosyltransferase
2.4.1.218
hydroquinone glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.35
phenol beta-glucosyltransferase
2.4.1.358
acylphloroglucinol glucosyltransferase
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR44152
KEGG:
R03594
MetaCyc:
SCOPOLETIN-GLUCOSYLTRANSFERASE-RXN
|
|
|
|
(E)-6''-hydroxyferulate <=> (Z)-6''-hydroxyferulate
|
5.2
|
–
|
| |
MetaCyc:
RXN-14070
|
|
|
|
2,4-dihydroxycinnamic_acid <=> (Z)-3-(2,4-dihydroxyphenyl)-prop-2-enoate
|
5.2
|
–
|
| |
MetaCyc:
RXN-14166
|
|
|
|
umbelliferone <=> esculetin
|
not assigned
|
–
|
| |
MetaCyc:
RXN-14165
|
|
|
|
esculin + H2O <=> esculetin + D-glucose
|
2.4.1
3.2.1.182
4-hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl glucoside beta-D-glucosidase
3.2.1.21
beta-glucosidase
3.2.1.78
mannan endo-1,4-beta-mannosidase
|
–
–
–
–
|
| |
BRENDA:
BS214486;
BS446940
MetaCyc:
RXN-13470
SABIO-RK:
14395
|
|
